2-({[4-(1,3-Benzothiazol-2-yl)phenyl]amino}methyl)phenol
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چکیده
In the title compound, C(20)H(16)N(2)OS, the aniline substituent essentially coplanar with the benzothia-zole moiety (with an r.m.s. deviation of all fitted non-H atoms of 0.0612 Å). The phenol group is almost perpendic-ular to the benzothia-zolylaniline group, with an inter-planar angle of 88.36 (2)°. In the crystal, mol-ecules aggregate as centrosymmetric dimers by pairs of O-H⋯N hydrogen bonds. C-H⋯O contacts and N-H⋯π(arene) inter-actions also occur.
منابع مشابه
2-{[4-(1,3-Benzothiazol-2-yl)phenyl](methyl)amino}acetic acid
In the title compound, C(16)H(14)N(2)O(2)S, the dihedral angle between the benzothia-zole ring system and benzene ring is 3.11 (2)°. In the crystal structure, inter-molecular O-H⋯N hydrogen bonds link mol-ecules into chains along [100] and these chains are, in turn, linked into a three-dimensional network via weak inter-molecular C-H⋯O hydrogen bonds.
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In the title compound, C(21)H(19)NO(3)S(2), the dihedral angles formed between the thia-zole ring and the adjacent benzene ring and the other benzene ring are 1.58 (3) and 76.48 (6)°, respectively. The crystal structure features a weak C-H⋯O inter-action.
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In the centrosymmetric dinuclear title compound, [Dy(2)(C(15)H(12)N(3)O(2)S)(2)(NO(3))(4)]·2CH(3)OH, the two Dy(III) atoms are coordinated by two deprotonated 2-{[2-(1,3-benzothia-zol-2-yl)hydrazinyl-idene]meth-yl}-6-meth-oxy-phenol ligands and four nitrate ions, all of which are chelating. The crystal packing is stabilized by inter-molecular N-H⋯O hydrogen bonds and weak O-H⋯O inter-actions, f...
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The title compound, C(20)H(12)N(2)S(2), was prepared by the reaction of o-phthalic acid and 2-amino-thio-phenol under microwave irradation. The phenyl ring, A, and the benzothia-zolyl rings, B and C, are planar; the dihedral angles are A/B = 19.9 (11), A/C = 87.8 (3) and B/C = 84.4 (4)°. Weak inter-molecular C-H⋯N hydrogen bonds link the mol-ecule, forming zigzag chains parallel to the c axis.
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The title compound, [Fe(2)(C(14)H(10)NS(2))(2)(CO)(6)], was synthesized as a structural and biochemical model for the active site of [FeFe]-hydrogenase. The bond lengths (Fe-Fe, Fe-S and Fe-C) and angles (C-Fe-Fe and Fe-S-Fe) are within expected ranges. The S⋯S distance [2.9069 (12) Å] and the dihedral angle between two Fe-S-Fe planes [78.5 (3)°] of the butterfly-shaped Fe(2)S(2) core are enlar...
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